| Commercial Name | Crude Glycerine 80% Min |
|---|---|
| Product Name | Crude Glycerine |
| Group of Chemicals | Glycerol |
| Common Name | Glycerol, Crude Glycerine, Crude Glycerin Gel, 1,2,3 Propanetriol |
| H.S Code | 1520.00.0000 |
| CAS Number | 56-81-5 (Primary Component Glycerol) |
| EC Number | 200-289-5 (Primary Component Glycerol) |
| Crude Glycerine 80% - Specification | Crude Glycerine 80% - Specification |
| SDS - Safety Data Sheet | Crude Glycerine 80% Min SDS - Safety Data Sheet - MSDS |
| TDS - Technical Data Sheet | Crude Glycerine 80% Min TDS - Technical Data Sheet |
| COA - Certificate of Analysis | Crude Glycerine 80% Min COA - Certificate of Analysis |
| Application of substance | Raw material for manufacturing Oleochemical derivatives for Pharmaceutical, Animal Feed and industrial use. Soap manufacturing Chemical intermediate, Paint, Pharmaceutical intermediate, Plasticizer |
| Details of the Manufacturer / Supplier | Mars Oleochemicals Sdn Bhd® |
| Kuala Lumpur, Malaysia | |
| Contact Person | Safety and Health Manager - Officer / Quality Control Manager - Chemist |
| info@marsoleo.com | |
| Telephone | +60 3 21175031 |
| Classification of substance | The product is not classified, according to the Globally Harmonized System (GHS). Product is non-hazardous Classification (in accordance with 29 CRF 1910.1200) | |
|---|---|---|
| Hazard Class | Hazard Category | Route of Exposure |
| Skin Irritation | Category 2 (Irritation) | Absorption |
| Eye Irritation | Category 2B (Mildly irritating) | Absorption |
| Signal Word | WARNING |
|
| Hazard statements | May cause skin and eye irritation | |
| Precautionary statements | Prevention: Wear appropriate protective gloves, protective garments and eye protection. | |
| Skin Contact | If on skin, wash thoroughly with soap and water. Take off contaminated clothing and wash it before reuse. If skin irritation or rash occurs, seek medical advice. | |
| Eye Contact | If in eyes, rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If irritation persists, seek medical attention. | |
| Environmental hazards | None identified. | |
| Storage | Store in cool tightly closed container. | |
| Disposal | Dispose of contents/container in accordance with local, state, and federal regulations. | |
| Hazards not otherwise specified | None | |
| Chemical Name | INCI Name | Formula | CAS No. | % of product |
|---|---|---|---|---|
| 1,2,3 - Propanetriol Glycerol | Glycerine, Glycerin | C3 H8 O3 | 56-81-5 | 75 - 85 |
| Aqua | Water | H2O | 7732-18-5 | 5 - 15 |
| Sodium Chloride | Salt | NaCl | 7647-14-5 | <8 |
| Methanol | Methanol | CH3OH | 67-56-1 | < 3 |
| General Information | Immediately remove any clothing soiled by the product. In case of adverse health effects seek medical advice. |
|---|---|
| After Inhalation | Supply fresh air; If suffocation is serious, get medical attention. consult doctor in case of complaints |
| After Skin contact | Immediately wash with water and soap and rinse thoroughly. Use gloves, absorb water from skin/body if contacted for too long Remove contaminated clothes. |
| After Eye contact | Use face shield, Remove contact lenses, Rinse opened eye for several minutes under running water. Then consult a doctor. |
| After Swallowing | Diarrhea, headache, nausea Remove material from mouth. Flush oral cavity, Drink plenty of water. If large amount Swallowed or symptoms develop obtain medical attention. |
| Information for Doctor | |
| Most important symptoms and effects, both acute and delayed | No further relevant information available. |
| Indication of any immediate medical attention needed | No further relevant information available. |
| Extinguishing Media | |
|---|---|
| Suitable fire-fighting agents | Use water mist, dry powder, firefighting foam, carbon dioxide for extinguishing |
| Extinguishing media which must not be used for safety reasons | A solid water stream, as it may scatter and spread the fire. |
| Specific hazards in the event of fire | Combustible, keep away from open flame, no smoking |
| Advice for firefighters | Protective clothing and self-contained breathing equipment should be carried Avoid breathing dust / fume / gas / mist / vapours / spray. |
| Protective equipment | Wear self-contained respiratory protective device. Wear fully protective suit. |
| Personal precautions, protective equipment and emergency procedures | Wear protective clothing. Use gloves, face shield Use respiratory protective device against the effects of fumes/dust/aerosol. |
| Environmental precautions | Do not allow product to reach sewage system or any water course. Inform respective authorities in case of seepage into water course or sewage system. Damp down dust with water spray. Do not allow to enter sewers / surface or ground water. |
| Methods and material for containment and cleaning up | Collect spillage in sealable containers, soak up with sand or other inert absorbent and remove to safe place. Flush away remainder with water. Dispose contaminated material as waste according to item 13. |
| Reference to other sections |
See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. |
| Precautions for safe handling | Keep receptacles tightly sealed and away from heat and direct sunlight. Ensure good ventilation/exhaustion at the workplace. Use protective chemical-resistant gloves and wear goggles when handling. |
| Information about fire - and explosion protection: | Keep ignition sources away - Do not smoke. Keep respiratory protective device available. |
| Conditions for safe storage | Store in the original closed containers. Keep in a cool and dry place, avoid extreme heat and cold. |
| Requirements to be met by storerooms and receptacles | Store only in the original receptacle. |
| Information about storage in one common storage facility | Store away from oxidizing agents. |
| Further information about storage conditions | Keep in a cool and dry place, avoid extreme heat and cold., avoid direct fire. Keep away from strong oxidizing agents, strong reducing agents, strong acid and strong bases. Store in clean, dry, preferably stainless-steel vessels. In bulk, store at ambient temperature. For pumping, heat up to above 60 °C. Temperature higher than necessary, will degrades quality at rate dependent on time and temperature of exposure. Exposure to ultraviolet light, especially sunlight must be minimized to prevent quality deterioration. |
| Specific end use(s) | No further relevant information available. |
| Additional information about design of technical facilities | No further data; see item 7. | |
| Control Parameters | ||
|---|---|---|
| Ingredients with limit values that require monitoring at the workplace: | ||
| 56-81-5 Glycerol PEL (Malaysia) Long-term value : 10 mg/m³ | ||
| Additional information | The lists valid during the making were used as basis. | |
| Exposure Controls | ||
| General protective and hygienic measures | The usual precautionary measures are to be adhered to when handling chemicals. Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. | |
| Personal protection | Hand protection: Suitable protective gloves. Eye protection: Protective goggles. Boday protection: Suitable protective clothing. | |
| Respiratory protection | Use suitable respiratory protective device only when aerosol or mist is formed. | |
| Protection of hands | Protective Gloves : The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation | |
| Material of Gloves : The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. |
|
|
| Penetration time of glove material : The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. | ||
| Eye Protection | Safety glasses | |
| Parameter | Value |
|---|---|
| Chemical Name | Crude Glycerin |
| Appearance : Form | Hygroscopic & viscous Yellowish-brownish liquid. |
| Form | Liquid - Viscous |
| Colour | Light to dark brown liquid |
| Odour | Mild oil odour |
| Melting point/freezing point | Above 18°C |
| Boiling point | Not Available |
| Flash point | Above 190°C (Cleveland open cup) |
| Density | About 1.2g/ml at 55°C |
| Flammability (solid, gas) | Not applicable |
| Water Solubility | infinite |
| Vapour pressure | Not available |
| Vapour density | Not available |
| Relative density | Not available |
| Solubility | Partially miscible with water |
| Partition coefficient (n-octanol/water) | Not available |
| Auto-ignition temperature | Not available |
| Decomposition temperature | Not available |
| Kinematic Viscosity @80°C | 214 mm 2/s |
| Molecular Weight | 92.1 g/mol (Glycerol) |
| Reactivity | When handled and stored appropriately, no dangerous reaction are known. |
| Chemical stability | Stable in closed containers at room temperature under normal storage and handling conditions. |
| Possibility of hazardous reactions | When handled and stored appropriately, no dangerous reaction are known. |
| Conditions to avoid | Ignition sources, accumulation of static electricity, heating product to its flash point, or allowing the product to cool below its melting point (otherwise, it may solidify and not transferable until it is reheated) See Section 7 for information of safe handling. |
| Incompatible materials | Keep away from strong oxidizing agents, strong reducing agents, strong acids and strong bases. See Section 7 for information of safe handling. |
| Hazardous decomposition products | Low toxicity and not considered hazardous to human beings |
| AcuteToxicity | ||
|---|---|---|
| LD50 (Oral,rat) = LC50 (Inhalation, rat) = | 23,000 mg/kg No Information was available | |
| Primary irritant effect: | ||
| Skin corrosion / irritation | May be mildly irritating to skin | |
| Serious eye damage / irritation | May be mildly irritating to the ayes | |
| Respiratory or skin sensitization | No sensitization reactions. | |
| Germ cell mutagenicity | Not likely to cause germ cell mutagenicity | |
| Carcinogenicity | Glycerol is not listed as a carcinogen | |
| Reproductive toxicity | Not available | |
| STOST-single / repeated exposure | Not available | |
| Aspiration hazard | Not available | |
| Toxicity | |
|---|---|
| Aquatic toxicity: | No adverse effect observed. |
| Acute fish toxicity: Acute EC50 (48h) | LC50 > 50000 mg/L (96 hours) - Glycerol |
| Invertebrates: | EC50 > 500 mg/L (24 hours) - Glycerol |
| Algae | No information available |
| Persistence and degradability | Readily biodegradable. |
| Glycerol | |
| Biodegradation in water | Accumulation in organisms is not be expected |
| Bioaccumulative potential | Accumulation in organisms is not be expected |
| Mobility in soil: | Will likely be mobile in the environment due to its water solubility but will likely degrade over time |
| Other adverse effect: | Not available |
| Waste treatment methods | Waste incineration with the approval of the responsible local authority |
| Recommendation | Must not be disposed together with household garbage. Do not allow product to reach sewage system. Must be specially treated adhering to official regulations. |
| Uncleaned packaging: Recommendation | Disposal must be made according to official regulations. |
| Not a hazardous material according to RID/ADR, GGVS/GGVE, ADNR, IMDG, ICAO-TI/IATADGR. | |
| UN-Number | Not Regulated |
| ADR/RID/ADN, IMDG, IATA | |
| UN proper shipping name | Not Regulated |
| ADR/RID/ADN, IMDG, IAT | |
| Transport hazard class(es) | Not Regulated |
| ADR/RID/ADN, ADN, IMDG, IATA Class | |
| Packing group | Not Regulated |
| ADR/RID/ADN, IMDG, IATA | |
| Environmental hazards | Not applicable |
| Special precautions for user | Not applicable |
| Transport in bulk according to Annex II of Marpol and the IBC Code | Product name : Glycerine |
| Pollution category: Z | |
| Ship type: 3 | |
| UN "Model Regulation" | Not Regulated |
| Classification and Identification | |
|---|---|
| Symbols of Danger | Not subject of the identification according to GefStoffV |
| Classification and labelling according to GHS | None |
| Classification and labelling according to EC | None |
| This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particulars properties. | |
| Department issuing SDS | Product Safety & Regulations Department |
| Contact: Product Safety & Regulations | Info@Marsoleo.com |
| This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. | |
| Department issuing SDS: | Product Safety & Regulations Department |
| Contact: Product Safety & Regulations | Info@Marsoleo.com |
| Abbreviations and Acronyms | |
|---|---|
| RA | Read-across |
| LLNA | Local Lymph Node Assay |
| NOAEL | No Observed Adverse Effect Level |
| NOEC | No Observed Effect Concentration |
| SCE | Sister Chromatid Exchange |
| OECD | Organisation for Economic Co-operation and Development |
| DNEL | Derived No-Effect Level |
| PNEC | Predicted No-Effect Concentration |
| STP | Sewage Treatment Plant |
| ADG | The Australian Code for the Transport of Dangerous Goods by Road & Rail |
| LoS | Limit of Solubility |
| SCL | Specific Concentration Limit |
| LOEC | Lowest Observed Effect Concentration |
| SSWL | Skin Surface Water Loss |
| IMDG | International Maritime Code for Dangerous Goods |
| IATA | International Air Transport Association |
| EINECS | European Inventory of Existing Commercial Chemical Substances |
| CAS | Chemical Abstracts Service (division of the American Chemical Society) |
| LC50 | Lethal concentration, 50 percent |
| LD50 | Lethal dose, 50 percent |
| PBT | Persistent, Bioaccumulative and Toxic |
| vPvB | very Persistent and very Bioaccumulative |
| Sources |
|---|
| CAS No. 56-81-5 Glycerol Annex 12 of Resolution MEPC.225(64) 2012 Amendments to The International Code For The Construction and Equipment of Ships Carrying Dangerous Chemicals in Bulk (IBC Code). |
| ECHA Registered Subtances Database, CAS No. 56-81-5. |
| Globally Harmonized System of Classification and Labelling of Chemicals (GHS), Third Revised Edition. |
| HSDB for CAS No. 56-81-5. |
| ICOP (2014). The Industry Code of Practice on Chemical Classification and Hazard Communication. |
| ICOP (2019). The Industry Code of Practice on Chemical Classification and Hazard Communication (Amendment). |
| ICSC (International Chemical Safety Card) 0624 (April 2006) Glycerol. |
| IMO (2020). IMDG Code International Maritime Dangerous Goods Code. Incorporating Amendment 40-20. |
| Official Journal of the European Union Commission Regulation (EU) No 453/2010. |
| Official Journal of the European Union Commission Regulation (EU) 2015/830. |
| Official Journal of the European Union Commission Regulation (EU) 2020/878. |
| Official Journal of the European Union Regulation (EC) No 1272/2008. |
| Official Journal of the European Union Regulation (EC) No 1907/2006. |
| P.U. (A) 310/2013. Occupational Safety Health (Classification, Labelling and Safety Data Sheet of Hazardous Chemicals) Regulations. |
| Data compared to the previous version altered. |
|
MARS OLEO® GLYCEROL Revision 1 (Mar 31, 2023) New issuance of GHS SDS according to ChemGes. Revision 2 (January 01, 2024) |
| Department issuing SDS : Product Safety & Regulations Department |
| Contact : Product Safety & Regulations - Info@Marsoleo.com |
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