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Glyceryl Monostearate - GMS SE 40 - Safety Data Sheet (SDS)

1. IDENTIFICATION OF THE PRODUCT / PREPARATION AND COMPANY

Commercial Name Glycerol Monostearate - GMS SE 40
Product Name Glycerol Monostearate GMS SE 40 / RSPO MB
Group of Chemicals Ester / Saturated Fatty Acid Derivative
INCI / Common Name Glyceride, C16-18-mono- And Di, Glyceryl Stearate, Glyceryl Monostearate, Glycerol Monostearate GMS, Glycerine Monostearate, Monostearate of Glycerol, GMS SE40, Glycerol Monostearate GMS SE 40
HS Code 2915.70.3000
CAS Number 31566-31-1 / 85251-77-0
EC Number 286-490-9
Molecular Formula C21H42O4
Glyceryl Monostearate-GMS SE 40 - Specification Glyceryl Monostearate-GMS SE 40 - Specification
SDS - Safety Data Sheet Glyceryl Monostearate-GMS SE 40 - Safety Data Sheet (SDS) - MSDS
TDS - Technical Data Sheet Glyceryl Monostearate-GMS SE 40 - Technical Data Sheet - TDS
COA - Certificate of Analysis Glyceryl Monostearate-GMS SE 40 - Certificate of Analysis - COA
Glycerol Monostearate Uses Additive for cosmetic and food application
Application of Glyceryl Monostearate Glycerol Monostearate - GMS SE 40 is a versatile self-emulsifying oleochemical ingredient widely applied in cosmetics, personal care, pharmaceuticals, food processing, and industrial formulations. It delivers excellent emulsifying, stabilizing, thickening, and moisturizing performance in creams, lotions, shampoos, conditioners, and skincare products. GMS SE 40 also improves texture, enhances product consistency, and supports smooth manufacturing processes, making it a preferred ingredient for high-quality cosmetic and industrial applications.
Details of the Manufacturer/Supplier Mars Oleochemicals Sdn Bhd®
Kuala Lumpur, Malaysia
Contact Person Safety and Health Manager - Officer / Quality Control Manager - Chemist
Email info@marsoleo.com
Telephone +60 3 21175031

2. HAZARDS IDENTIFICATION OF THE PRODUCT

Emergency Overview Non-hazardous.
Physical Appearance Powder/ Flakes
Immediate Concerns None
Eye Dust can cause irritation. Symptoms include stinging, tearing redness and swelling of eyes. Unlikely to cause any irritation or injury.
Skin Unlikely to cause any skin\irritation or injury. This material is unlikely to pass into the body through the skin.
Inhalation This material is a dust or may produce dust. Breathing small amounts of this material is not harmful.
Signs and Symptoms of Overexposure Signs and symptoms of exposure of this material through breathing, swallowing and/or passage of the material through the skin may include: stomach and intestinal upset (nausea, vomiting and diarrhea) irritation (nose, throat and airways)
Target Organ Statement Non-hazardous and non-toxic material.
Carcinogenicity Not listed by International Agency for Research on Cancer, the National Toxicology Program or the Occupational Health and Safety Organization.
Mutagenicity Not Available
Reproductive Toxicity
Reproductive Effects Not Available
Teratogenic Effects Not Available
Medical Conditions Aggravated None Known
Sensitization Not Available

3. COMPOSITION / INFORMATION ON INGREDIENTS

General Chemical Description Glycerol Monostearate-GMS SE 40
Chemical Family Ester / Fatty ACID Ester
Chemical Name Glyceride, C16-18-mono and di
CAS Number 31566-31-1 / 85251-77-0
Molecular Formula C21H42O4
H.S Code 2915.70.3000
Physical Appearance Creamish White or White Powder / Flakes
COMPOSITION AND INFORMATION OF THE INGREDIENTS OF THE HAZARDOUS CHEMICAL
Dangerous Components
Chemical Name CAS No EINECS No % by wt.
Glyceryl Monostearate 31566-31-1 286-490-9 -
Additional information This product is not classified as hazardous to health or environment according to GHS.

4. FIRST AID MEASURES

Description of First aid Measures
After Inhalation Remove from further exposure. If vapors or mist cause irritation or distress, remove to fresh air. If symptoms persist, seek medical attention. If breathing is difficult administer oxygen. Keep person warm and quiet.
After Skin contact First aid is not normally required however it is recommended that exposed area be cleaned by washing with soap and water.
After Eye contact Immediately flush eyes with plenty of water. Remove any contact lenses and continue flushing for 15 minutes with eyelids wide open. Have immediate medical attention.
After Ingestion If individual is drowsy or unconscious, do not give anything by mouth, place individual on his left with his head down. Contact a physician, medical facility for advice as to whether to induce vomiting. Seek immediate medical attention.
Information for doctor Pre-existing disorders of the following type may be aggravated by exposure to this material lung (for example, asthma like conditions)

5. FIRE - FIGHTING MEASURES

Flash Point and Method 148.8 ° C (300°F) COC
Flammable Limits No data available
Autoignition Temperature Not available
General Hazard Evacuate personnel downwind of fire to avoid inhalation of irritating fumes and smoke.
Extinguishing Media Regular foam large, alcohol foam, water fog, carbon dioxide, dry chemical.
Hazardous Combustion Products Carbon monoxide and carbon dioxide from burning or various hydrocarbons.
Fire Fighters Procedures Water and foam may cause frothing which can be violent and possibly endanger the life of fire-fighter. Water may use to keep the fire exposed containers coo until the fire is out. Wear a self-contained breathing apparatus with a full-face piece operated with positive pressure demand mode with appropriate turn out gear and chemical resistant personal protective equipment. Refer to the personal protective equipment section of MSDS.
Sensitivity to Static Discharge Not available
Sensitivity to Impact Not available
NFPA Rating Health – 1. Flammability – 0, Reactivity – 0

6. ACCIDENTAL RELEASE MEASURES

Small Spill Scoop or scrap up. Put in container for recovery or disposal.
Large Spill Persons not wearing protective equipment should be excluded from the areas of spill until clean-up is completed. Shovel material into containers. Thoroughly clean up the area of spill to clean up any residual material.
Environmental precautions Water Spill Use appropriate containment to avoid runoff or release to sewer or waterways.
Land Spill Land Spill
General Procedures Remove containers of strong acids from release area.
Release Notes If spill could potentially enter any waterway, including intermittent dry creeks, contact local authorities.
Large and small spills may have a broad definition depending on the user’s handling system. Therefore, technically qualified personnel must define the spill category at the point of release.Large and small spills may have a broad definition depending on the user’s handling system. Therefore, technically qualified personnel must define the spill category at the point of release.

7. HANDLING AND STORAGE

Precautions for safe Handling
Advice on safe handling When using do not eat, drink or smoke. The usual precautions for handling chemicals should be observed. Avoid Incompatible materials (See Section 10). Avoid dust formation. Ensure adequate ventilation.
Advice on protection against fire and explosion Avoid dust generation. Provide adequate ventilation places where dust is at formed.
Conditions for Safe Storage, including any Incompatibilities
Requirements for storage Store in original container.
Further information about storage conditions Keep container tightly closed areas and containers in a dry and well-ventilated place. Store in a dry place and/or in closed container.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Engineering Controls Use adequate ventilation to maintain exposure below over- exposure known to cause suspected or apparent adverse effects.
Personal Protective Equipment
Eyes and Face Wear safety glasses in compliance with OSHA regulations.
Protective Clothing Wear resistant gloves such as natural rubber. Wear normal work clothing covering arms and legs.
Respiratory Protection Ordinary not needed.
Work Hygienic Practices Use in a manner consistent with good industrial / manufacturing techniques and practices.

9. PHYSICAL & CHEMICAL PROPERTIES

Parameter Value
Chemical Name Glyceryl Monostearate
Appearance Creamish White or White Powder / Flakes
Iodine Value 2.0 Max.
Lovibond 5 ¼” Cell 1.5R 10.0Y Max.
Melting Point 58°C ± 3
Saponification Value 150 - 165
Free Glycerine 5 Max
Monoester Content 40 - 45% Min.
Moisture Content 2.0 Max.
Acid Value 3.0 Max.
Soap Content 5.0 Max.

10. STABILITY AND REACTIVITY

Stable Product is stable under normal conditions of temperature and pressure.
Reactivity Product is stable under normal conditions of temperature and pressure.
Possibility of hazardous reactions Reactions with strong oxidizing agents.
Conditions to avoid Incompatible materials, strong oxidants.
Hazardous Polymerization Will not occur
Incompatible Materials Strong oxidizing agents and strong alkali or caustic

11. TOXICOLOGICAL INFORMATION

Mutagenicity Not Available
Acute Toxicity No Data Available
Skin Corrosion / Irritation No Data Available
Respiratory or Skin Sensitization No Data Available
Carcinogenicity No Data Available
STOST-single / repeated exposure No Data Available
Aspiration Hazard No Data Available
Reproductive Effects No Data Available
Teratogenic Effects No Data Available

12. ECOLOGICAL INFORMATION

Environmental Data No Data
Aquatic Toxicity
Acute fish Toxicity No Data Available
Acute Bacteria Toxicity No Data Available
Persistence and Degradability No Data Available
Bioaccumulative Potential No Data Available
Mobility in Soil No Data Available

13. DISPOSAL CONSIDERATIONS

Disposal Method Dispose of waste at an appropriate waste disposal facility according to current applicable state or local laws and regulations.

14. TRANSPORT INFORMATION

Not a hazardous material according to RID/ADR, GGVS/GGVE, ADNR, IMDG, ICAO-TI/IATADGR.
UN-Number Not Regulated
UN Proper Shipping Name
Land Transport (ADR/RID) Not Regulated
Maritime Transport (IMDG) Not Regulated
Air Transport (IATA) Not Regulated
Transport Hazard Class(es)
Land Transport (ADR/RID) Not Regulated
Maritime Transport (IMDG) Not Regulated
Air Transport (IATA) Not Regulated
Packing Group
Land Transport (ADR/RID) Not Regulated
Maritime Transport (IMDG) Not Regulated
Air Transport (IATA) Not Regulated
Environmental Hazards
Special Precautions for User Not Applicable
Maritime Transport in Bulk Annex II of MARPOL 73/78 and the IBC Code Not Applicable
UN "Model Regulation" Not Regulated

15. REGULATORY INFORMATION

Safety, health and environmental regulations / legislation specific for the substance or mixture
EHS reference list Substance is not listed.
GHS label elements Not Applicable
Hazard Pictograms Not Applicable
Signal Word Not Applicable
Hazard statements Not Applicable
Directive 2012/18/EU Substance is not listed.
Named dangerous substances - ANNEX I
Other Rregulations, Llimitations and Prohibitive Regulations
Positive Country Substance Listing for CAS No. 31566-31-1 USA (TSCA), Canada (DSL), Europe (EINECS): 203-751-4, Australia (AIIC), Japan (ENCS): 2-798, Korea (KECI/ KECL): KE-33355, China (IECSC): 28352, China (IECIC): 05608, Philippines (PICCS), New Zealand (NZIoC), Taiwan (TCSI), Mexico (INSQ), Thailand (TECI), Vietnam (VNCI).
Note The substance name and CAS numbers which are used for this product in the stated inventories may deviate from the information listed in Section 3.
Chemical safety assessment A Chemical Safety Assessment has been carried out.

16. OTHER INFORMATION

The information provided in this Safety Data sheet is correct to the best of Mars Oleochemicals knowledge, information and belief at the date of its publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release, and is not to be considered a warranty or quality specification. The information relates only to the specific product designated and may not be valid for such product when used in combination with any other material or in any process, unless specified in this SDS. MARS OLEO specifically disclaims any liability for any loss, injury or damage which may result from user or misuse of this product.
All chemicals should be handled only by competent personnel, within a controlled environment. It is the buyers/ user's responsibility to ensure that his activities comply with all applicable federal, state, provincial and local laws, and to determine the conditions necessary for the safe user of this product. MARS OLEOCHEMICALS urges each customer or recipient of this SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product.
Abbreviations and Acronyms
RID Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail)
ICAO International Civil Aviation Organisation
NOAEL No Observed Adverse Effect Level
RA Read-Across
LDLo Lowest Published Lethal Dose
VOID Not regulated / Not Classified / Not a Dangerous Good
LoS Limit of Solubility
COS Cornea Opacity Score
COC Cleveland Open Cup
ADR Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road)
PNEC Predicted No-Effect Concentration (REACH)
DNEL Derived No-Effect Level
LOEC Lowest Observed Effect Concentration
SSWL Skin Surface Water Loss
IMDG International Maritime Code for Dangerous Goods
IATA International Air Transport Association
EINECS European Inventory of Existing Commercial Chemical Substances
CAS Chemical Abstracts Service (division of the American Chemical Society)
LC50 Lethal concentration, 50 percent
LD50 Lethal dose, 50 percent
PBT Persistent, Bioaccumulative and Toxic
vPvB very Persistent and very Bioaccumulative

16. OTHER INFORMATION

Sources
CAS No. 31566-31-1 GMS NE 40
Annex 12 of Resolution MEPC.225(64) 2012 Amendments to The International Code for The Construction and Equipment of Ships Carrying Dangerous Chemicals in Bulk (IBC Code).
ECHA Substance Registered Database for CAS No. 31566-31-1.
Globally Harmonized System of Classification and Labelling of Chemicals (GHS), Sixth & Seventh Revised Edition.
HSDB for CAS No. 31566-31-1.
IMO (2007). IBC Code 2007 Edition.
IMO (2014). IMDG Code International Maritime Dangerous Goods Code. Incorporating Amendment 37-14. 2014 Edition, Volume 1 & 2.
ICOP (2014). The Industry Code of Practice on Chemical Classification and Hazard Communication.
ICOP (2019). The Industry Code of Practice on Chemical Classification and Hazard Communication (Amendment).
IMO (2020). IMDG Code International Maritime Dangerous Goods Code. Incorporating Amendment 40-20.
P.U. (A) 310/2013. Occupational Safety Health (Classification, Labelling and Safety Data Sheet of Hazardous Chemicals) Regulations.
Data Compared to the Previous Version Altered.
Department issuing SDS : Product Safety & Regulations Department
Contact : Product Safety & Regulations - sales@marsoleo.com
SDS Updated Date : 1 Jan 2025
SDS Creation Date : 31 March 2023
Version : 2.00
Disclaimer : This Safety Data Sheet does not constitute any warranty or guarantee as to the quality, properties, condition or otherwise of the product. It has been prepared from the best knowledge available to us and we shall not be liable for any insufficiency or inaccuracy in such information in any case whatsoever.

CERTIFICATIONS

  • This product is manufactured in facility certified as per ISO 9001 9001:2015, FSSC 22000, GMP+B2 by Lloyd’s Register Quality Assurance and RSPO Supply Chain MB Certification Standard Certified by SIRIM (MALAYSIA)
  • This product is Kosher certified by OK Kosher Certification (USA)
  • This product is certified Halal by JAKIM (MALAYSIA)
  • This product is derived entirely from 100% vegetable-based sources, ensuring a natural, sustainable, and eco-friendly origin.
  • Adheres to Non-Genetically Modified Organism (Non-GMOs) production standard. This product is Certified 100% GMO-free.

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