| Commercial Name | Oleic Acid 75% |
|---|---|
| Product Name | Oleic Acid 75% / RSPO MB |
| Group of Chemicals | Fatty Acid |
| INCI / Common Name | Oleic Acid 75% / Octadecenoic Acid / Fatty Acid C18 unsaturated. |
| H.S Code | 3823.12.0000 |
| CAS Number | 112-80-1 / CAS number: 67701-08-0 |
| EC Number | 204-007-1 |
| Oleic Acid 75% - Specification | Oleic Acid 75% - Specification |
| SDS - Safety Data Sheet | Oleic Acid 75% SDS - Safety Data Sheet - MSDS |
| TDS - Technical Data Sheet | Oleic Acid 75% TDS - Technical Data Sheet |
| COA - Certificate of Analysis | Oleic Acid 75% COA - Certificate of Analysis |
| Application of substance | Esters production - Used to make oleate esters for lubricants, plasticizers, and emulsifiers, Soaps & Detergents - Key raw material for soft soaps and specialty cleaning agents, Cosmetics & Personal Care Products - Found in creams, lotions, moisturizers, and hair care products as an emollient , Lubricants - Used in metalworking fluids and biodegradable lubricants, Metallic soaps - Forms calcium, zinc, and aluminum oleates used in greases and stabilizers, Coatings & Paints - Acts as a dispersing agent and improves film formation, Adhesives & Sealants -- Enhances flexibility and spreadability, Industrial chemicals - Intermediate for surfactants, emulsifiers, and corrosion inhibitors, Laboratory Chemicals - Used in analytical reagents and research formulations, Oleochemicals - Raw material for fatty alcohols, fatty amines, and other derivatives, Textile industry - Used as a softening and finishing agent, Rubber & Plastics - Functions as a processing aid and plasticizer, Pharmaceuticals - Used as an excipient and drug delivery enhancer, Food industry - Used as a food additive and flavor carrier (in regulated forms), |
| Details of the Manufacturer / Supplier | Mars Oleochemicals Sdn Bhd® |
| Kuala Lumpur, Malaysia | |
| Contact Person | Safety and Health Manager - Officer / Quality Control Manager - Chemist |
| info@marsoleo.com | |
| Telephone | +60 3 21175031 |
| Classification of substance | The product is not classified, according to the Globally Harmonized System (GHS). |
|---|---|
| Product is non-hazardous | |
| Skin Contact | Not irritating |
| Environmental hazards | None identified. |
| Label Elements | |
| GHS label elements | Not applicable |
| Hazard pictograms | Not applicable |
| Signal word | Not applicable |
| Hazard statements | Not applicable |
| Results of PBT assessment | This product is not classified as PBT. |
| Results of vPvB assessment | This product is not classified as vPvB. |
| General Chemical Description | Oleic Acid 75% |
|---|---|
| Chemical Family | Fatty Acid |
| Chemical Name | Oleic Acid 75% / Octadecenoic Acid / Fatty Acid C18 unsaturated. |
| Molecular Formula | C18H34O2 |
| H.S Code | 3823.12.0000 |
| EC number | 204-007-1 |
| Additional information | This product is not classified as hazardous to health or environment according to GHS. |
| Chemical Name | CAS Number. | EINECS Number | % by wt. |
|---|---|---|---|
| Oleic Acid (C18:1) 75%, Octadecenoic Acid / Fatty Acid C18 unsaturated. | 112-80-1 Alternative CAS - 67701-08-0 | 204-007-1 | 75 |
| Fatty Acids, C14-18 | 67701-02-4 67701-02-4 | - | 9 |
| Linoleic acid (C18:2) | 60-33-3 | - | 16 |
| General Information | No special measures required |
|---|---|
| After Inhalation | Supply fresh air. In case of breathing difficulty, try artificial respiration. Get medical attention as soon as possible. |
| After Skin contact | Immediately wash with water and soap and rinse thoroughly. If skin irritation continues, consult a doctor |
| After Eye contact | Rinse cautiously with water for several minutes. Remove contact lenses, If symptoms persist, immediately seek medical attention |
| After Swallowing | Do not induce vomiting; call for medical help immediately. Rinse out mouth and then drink plenty of water. Call a doctor immediately. |
| Information for Doctor | |
| Most important symptoms and effects, both acute and delayed | No further relevant information available. |
| Indication of any immediate medical attention and special treatment needed | No further relevant information available. |
| Extinguishing Media | |
|---|---|
| Suitable extinguishing agents | Sand, CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Use fire extinguishing methods suitable to surrounding conditions. |
| For safety reasons unsuitable extinguishing agents | Water with full jet |
| Special hazards arising from the substance or mixture | No further relevant information available. |
| Specific hazards in the event of fire | Combustible, keep away from open flame, no smoking. |
| Advice for Firefighters | Avoid breathing dust / fume / gas / mist / vapours / spray. |
| Protective equipment | Wear self-contained respiratory protective device. Wear fully protective suit. |
| Personal precautions, protective equipment and emergency procedures | Wear protective clothing and equipment. Keep unprotected persons away. Use respiratory protective device against the effects of fumes / dust / aerosol |
| Environmental precautions | Do not allow product to reach sewage system or any water course. Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water. |
| Methods and material for containment and cleaning up | Collect the spillage in the containers and remove to safe place. After collecting the spillage, wash with plenty of water. Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose of the material collected according to regulations. |
| Reference to other sections |
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment. See Section 13 for disposal information. |
| Precautions for safe handling | Ensure good ventilation/exhaustion at the workplace. Open and handle receptacle with care. Keep away from heat and direct sunlight. |
|---|---|
| Information about fire - and explosion protection | Keep ignition sources away - Do not smoke. Keep respiratory protective device available. |
| Conditions for safe storage | Store in tightly sealed, cool, well-ventilated and dry place. Store only in the original receptacle. Keep away from heat, strong acids and oxidizing agents. |
| Information about storage in one common storage facility | Store away from oxidizing agents. |
| Further information about storage conditions | Keep container tightly sealed. Protect from heat and direct sunlight. |
| Specific end use(s) | No further relevant information available. |
| Control parameters | ||
|---|---|---|
| Ingredients with limit values that require monitoring at the workplace | Not required. | |
| Exposure Controls | ||
| General protective and hygienic measures: | The usual precautionary measures are to be adhered to when handling chemicals. Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. | |
| Respiratory protection | Suitable respiratory protective device recommended. | |
| Personal protection | Hand protection: Suitable protective gloves. Eye protection: Protective goggles. Boday protection: Suitable protective clothing. | |
| Protection of hands | Protective Gloves : The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation | |
| Material of Gloves : The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. |
|
|
| Penetration Time of Glove Material : The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. | ||
| Eye Protection | Tightly sealed Safety glasses |
|
| Other Information | Follow standard industrial practice for handling chemicals | |
| Parameter | Value |
|---|---|
| Chemical Name | Oleic Acid 75% / Octadecenoic Acid / Fatty Acid C18 unsaturated. |
| Appearance: Form | Liquid Yellow |
| Colour | Clear |
| Odour | Characteristic |
| Odour threshold | Not Determined |
| pH Value | Not Determined |
| Change in Condition | |
| Melting point / freezing poin | ca. 7 - 11 °C |
| Boiling point/boiling range | ca. 286 °C (at 100 mmHg) |
| Flammability (solid, gas) | Product is not flammable. |
| Auto-ignition Temp | ca. 363 °C (ICSC 1005) |
| Flash point | 220 °C (ASTM D92, COC) |
| Decomposition temperature | Not Determined |
| Ignition temperature | Not Determined |
| Explosive properties | Product does not present an explosion hazard. |
| Lower Explosion Limit | Not Determined |
| Upper Explosion Limit | Not Determined |
| Vapour pressure at 25 °C | ca. 5.46 x 10-7 mmHg (HSDB) |
| Density at 25 °C | ca. 0.895 g/cm³ (HSDB) |
| Relative Density at 20 °C | Not determined |
| Vapour Density | Not applicable |
| Evaporation rate | Not applicable |
| Solubility in/Miscibility with water | Insoluble |
| Partition coefficient : n-octanol/water | 7.64 log Pow (HSDB) |
| Viscosity | |
| Dynamic | Not Applicable |
| Kinematic | Not Applicable |
| Other Safety Characteristics | Not Applicable |
| Reactivity | No further relevant information available. |
| Chemical stability | Stable at environment temperature. |
| Thermal Decomposition / Conditions to be avoided | No decomposition if used according to specifications. |
| Possibility of Hazardous Reactions | No dangerous reactions known. |
| Conditions to Avoid | See Section 7 for information of safe handling. |
| Incompatible Materials | See Section 7 for information of safe handling. |
| Hazardous Decomposition Products | Irritant gases / vapours Carbon monoxide and carbon dioxide. |
| Information on Toxicological Effects | |||
|---|---|---|---|
| Acute toxicity | |||
| LD/LC50 values relevant for classification | Oral | LD50 | > 19,243 mg/kg bw (Rat) (IUCLID 2000e) |
| 112-80-1 Oleic Acid | Dermal | LD50 | >3,000 mg/kg bw (Guinea pig) (IUCLID 2000e) |
| Primary Irritant Effect | |||
| Skin corrosion / irritation | Based on available data, the classification criteria are not met. | ||
| Serious eye damage or eye irritation | Based on available data, the classification criteria are not met. | ||
| Respiratory or skin sensitization | Based on available data, the classification criteria are not met. | ||
| Additional Toxicological Information | |||
| Repeated dose Toxicity | Oral | NOAEL | ||
| 112-80-1 Oleic Acid | >7,500 mg/kg bw/day (Rat) (IUCLID, 2000e) | ||
| CMR Effects (Carcinogenity, Mutagenicity and Toxicity for Reproduction) | |||
| Germ cell mutagenicity | Based on available data, the classification criteria are not met. | ||
| 112-80-1 Oleic Acid | Mutagenicity - (Salmonella typhimurium) (Negative (CCRIS Oleic acid)) | ||
| Carcinogenicity | Based on available data, the classification criteria are not met. | ||
| Reproductive Toxicity | Based on available data, the classification criteria are not met. | ||
| Toxicity for reproduction | Based on available data, the classification criteria are not met. | ||
| Specific target organ toxicity (STOT) - single exposure | Based on available data, the classification criteria are not met. | ||
| Specific target organ toxicity (STOT) - repeated exposure | Based on available data, the classification criteria are not met. | ||
| Aspiration Hazard | Based on available data, the classification criteria are not met. | ||
| Toxicity | |
|---|---|
| Aquatic toxicity : 112-80-1 Oleic Acid | |
| LC50 (96h) | 205 mg/L (Fish) (HSDB, CAS # 112-80-1) |
| LC50 (48) (static) | 252 mg/L (Fish) |
| Persistence and Degradability | Readily biodegradable. |
| Other information | CAS No. 112-80-1: |
| OECD Guideline 301C (Modified MITI Biodegradation Test) | |
| 78% degradation after 28 days | |
| Behaviour in Environmental Systems | |
| Bioaccumulative Potential | Log Kow 7.64 |
| Mobility in soil | No further relevant information available. |
| Additional Ecological Iinformation | |
| General Notes | Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. |
| Result of PBT and vPvB assessment | |
| PBT | No |
| vPvB | No |
| Other Adverse Effects | No further relevant information available. |
| Waste treatment methods | Recommendation Must be specially treated adhering to official regulations. |
| Uncleaned Packaging Recommendation | Disposal must be made according to official regulations. |
| Not a hazardous material according to RID/ADR, GGVS/GGVE, ADNR, IMDG, ICAO-TI/IATADGR. | |
| UN-Number | Not regulated |
| UN Proper Shipping Name | |
| Land Transport (ADR/RID) | Not regulated |
| Maritime Transport (IMDG) | Not regulated |
| Air Transport (IATA) | Not regulated |
| HS Code | 3823.12.0000 |
| Transport Hazard Class(es) | |
|---|---|
| Land Transport (ADR/RID) | Not Regulated |
| Maritime Transport (IMDG) | Not Regulated |
| Air Transport (IATA) | Not Regulated |
| Packing Group | |
| Land Transport (ADR/RID) | Not Regulated |
| Maritime Transport (IMDG) | Not Regulated |
| Air Transport (IATA) | Not Regulated |
| Environmental Hazards | |
| Marine Pollutant (Yes/No) | No |
| Special Precautions for User | Not Applicable |
| Maritime Transport in Bulk Annex II of MARPOL 73/78 and the IBC Code | Not Applicable |
| UN "Model Regulation" | Not Regulated |
| Safety, health and environmental regulations / legislation specific for the substance or mixture | |
| EHS reference list | Substance is not listed. |
| GHS label elements | Not applicable |
| Hazard pictograms | Not applicable |
| Signal word | Not applicable |
| Hazard statements | Not applicable |
| Directive 2012/18/EU Named dangerous substances - ANNEX I | Substance is not listed |
| Positive Country Substance Listing for CAS No. 112-80-1 | USA (TSCA), Canada (DSL), Europe (EINECS) : 204-007-1, Japan (ENCS): 2-975 / 2-609, Australia (AIIC), Korea (KECI/KECL): KE-26450, China (IECSC) : 30310, Philippines (PICCS), New Zealand (NZIoC), Taiwan (TCSI), Mexico (INSQ), Vietnam (VNCI), Thailand (TECI) |
| Note | The substance name and CAS numbers which are used for this product in the stated inventories may deviate from the information listed in Section 3. |
| Positive Country Substance Listing for CAS No. 67701-08-0 (alternative CAS) | USA (TSCA), Canada (DSL), Europe (EINECS) : 266-932-7, Australia (AIIC), Korea (KECI/KECL) : KE-35126, Japan (ENCS) : 2-608 / 2-609, China (IECSC) : 04852, Philippines (PICCS), New Zealand (NZIoC), Taiwan (TCSI), Vietnam (VNCI). |
| Chemical safety assessment | A Chemical Safety Assessment has been carried out. |
| The information provided in this Safety Data sheet is correct to the best of Mars Oleochemicals knowledge, information and belief at the date of its publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release, and is not to be considered a warranty or quality specification. The information relates only to the specific product designated and may not be valid for such product when used in combination with any other material or in any process, unless specified in this SDS. MARS OLEO specifically disclaims any liability for any loss, injury or damage which may result from user or misuse of this product. | |
| All chemicals should be handled only by competent personnel, within a controlled environment. It is the buyers/ user's responsibility to ensure that his activities comply with all applicable federal, state, provincial and local laws, and to determine the conditions necessary for the safe user of this product. MARS OLEOCHEMICALS urges each customer or recipient of this SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. | |
| Abbreviations and Acronyms | |
|---|---|
| RID | Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) |
| ICAO | International Civil Aviation Organisation |
| BCF | Bioconcentration Factor |
| NOAEL | No Observed Adverse Effect Level |
| RA | Read-Across |
| LDLo | Lowest Published Lethal Dose |
| VOID | Not regulated / Not Classified / Not a Dangerous Good |
| LoS | Limit of Solubility |
| COS | Cornea Opacity Score |
| COC | Cleveland Open Cup |
| ADR | Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road) |
| LLNA | Local Lymph Node Assay |
| NOEC | No Observed Effect Concentration |
| OECD | Organisation for Economic Co-operation and Development |
| DNEL | Derived No-Effect Level |
| STP | Sewage Treatment Plant |
| ADG | The Australian Code for the Transport of Dangerous Goods by Road & Rail |
| SCL | Specific Concentration Limit |
| LOEC | Lowest Observed Effect Concentration |
| SSWL | Skin Surface Water Loss |
| IMDG | International Maritime Code for Dangerous Goods |
| IATA | International Air Transport Association |
| EINECS | European Inventory of Existing Commercial Chemical Substance |
| CAS | Chemical Abstracts Service (division of the American Chemical Society) |
| LC50 | Lethal concentration, 50 percent |
| LD50 | Lethal dose, 50 percent |
| PBT | Persistent, Bioaccumulative and Toxic |
| vPvB | very Persistent and very Bioaccumulative |
| Skin Corr. 1 | Skin corrosion or irritation - Category 1 |
| Skin Irrit. 2 | Skin corrosion or irritation - Category 2 |
| Eye Dam. 1 | Serious eye damage or eye irritation - Category 1 |
| Eye Irrit. 2 | Serious eye damage or eye irritation - Category 2 |
| Aquatic Chronic 3 | Hazardous to the aquatic environment - chronic hazard - Category 3 |
| Sources |
|---|
| Annex 12 of Resolution MEPC.225(64) 2012 Amendments to The International Code for The Construction and Equipment of Ships Carrying Dangerous Chemicals in Bulk (IBC Code). |
| Globally Harmonized System of Classification and Labelling of Chemicals (GHS), Third Revised Edition. HSDB for CAS No. 112-80-1. |
| ICSC (International Chemical Safety Card) # 1005 for Oleic Acid. |
| IMO (2007). IBC Code 2007 Edition. |
| IMO (2014). IMDG Code International Maritime Dangerous Goods Code. Incorporating Amendment 37-14. 2014 Edition, Volume 1 & 2. |
| IUCLID Dataset; Substance ID: 112-80-1-year 2000. |
| ICOP (2014). The Industry Code of Practice on Chemical Classification and Hazard Communication. |
| ICOP (2019). The Industry Code of Practice on Chemical Classification and Hazard Communication (Amendment). |
| IMO (2020). IMDG Code International Maritime Dangerous Goods Code. Incorporating Amendment 40-20. |
| Official Journal of the European Union Commission Regulation (EU) No 453/2010. |
| Official Journal of the European Union Commission Regulation (EU) No 453/2010. |
| Official Journal of the European Union Commission Regulation (EU) 2015/830. |
| Official Journal of the European Union Regulation (EC) No 1272/2008. |
| Official Journal of the European Union Regulation (EC) No 1907/2006. |
| P.U. (A) 310/2013. Occupational Safety Health (Classification, Labelling and Safety Data Sheet of Hazardous Chemicals) Regulations. |
| Data Compared to the Previous Version Altered. |
|
MARS OLEOCHEMICALS® Revision 1 (Mar 31, 2023) New issuance of GHS SDS according to ChemGes. Revision 2 (January 01, 2025) |
| Department issuing SDS : Product Safety & Regulations Department |
| Contact: Product Safety & Regulations sales@marsoleo.com |
| SDS Updated Date : 1 Jan 2025 |
| SDS Creation Date : 31 March 2023 |
| Version : 2.00 |
| Disclaimer |
| This Safety Data Sheet does not constitute any warranty or guarantee as to the quality, properties, condition or otherwise of the product. It has been prepared from the best knowledge available to us and we shall not be liable for any insufficiency or inaccuracy in such information in any case whatsoever. |
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