| Commercial Name | Refined Glycerine 99.7% Min USP |
|---|---|
| Product Name | Refined Glycerine |
| Group of Chemicals | Glycerol |
| Common Name | Glycerol, Glycerine, Glycerin, 1,2,3 Propanetriol |
| H.S Code | 2905.45.0000 |
| CAS Number | 56-815 |
| EC Number | 200-289-5 |
| Refined Glycerine 99.7% USP - Specification | Refined Glycerine 99.7% USP - Specification |
| SDS - Safety Data Sheet | Refined Glycerine 99.7% Min USP SDS - Safety Data Sheet - MSDS |
| TDS - Technical Data Sheet | Refined Glycerine 99.7% Min USP TDS - Technical Data Sheet |
| COA - Certificate of Analysis | Refined Glycerine 99.7% Min USP COA - Certificate of Analysis |
| Application of substance | Raw material for manufacturing Oleochemical derivatives for Pharmaceutical, Food, Cosmetics and industrial use. Chemical intermediate, Food, Moisturizing, Paint, Pharmaceutical intermediate, Plasticizer, Textile auxiliary |
| Details of the Manufacturer / Supplier | Mars Oleochemicals Sdn Bhd® |
| Kuala Lumpur, Malaysia | |
| Contact Person | Safety and Health Manager - Officer / Quality Control Manager - Chemist |
| info@marsoleo.com | |
| Telephone | +60 3 21175031 |
| Classification of substance | The product is not classified, according to the Globally Harmonized System (GHS). |
|---|---|
| Product is non-hazardous | |
| Skin Contact | Not irritating. |
| Environmental hazards | None identified |
| Label Elements | |
| GHS label elements | Not applicable |
| Signal word | Not applicable |
| Results of PBT assessment | This product is not classified as PBT. |
| Results of vPvB assessment | This product is not classified as vPvB. |
| General Chemical Description | Glycerine, 1,2,3 -Propanetriol, formula C3 H8 O3 |
|---|---|
| Chemical Formula | C3 H8 O3 |
| CAS No | 56-81-5 |
| EINECS Number | 266-928-5 |
| Ingredients | |
| H.S Code | 2905.45.0000 |
| Physical Appearance | Clear, Colorless liquid |
| General Information | Immediately remove any clothing soiled by the product. In case of adverse health effects seek medical advice. |
|---|---|
| After Inhalation | Supply fresh air; consult doctor in case of complaints. |
| After Skin contact | Immediately wash with water and soap and rinse thoroughly.Remove contaminated clothes. |
| After Eye contact | Rinse opened eye for several minutes under running water. Then consult a doctor. |
| After Swallowing | Remove material from mouth. Flush oral cavity, Drink plenty of water. If large amount Swallowed or symptoms develop obtain medical attention. |
| Information for doctor: | |
| Most important symptoms and effects, both acute and delayed | No further relevant information available. |
| Indication of any immediate medical attention needed | No further relevant information available. |
| Extinguishing Media | |
|---|---|
| Suitable Extinguishing agents: | CO2, powder or water spray. Fight larger fires with water spray. Or alcohol resistant foam. |
| For safety reasons unsuitable extinguishing agents: | Water with full jet. |
| Special hazards arising from the substance or mixture | Under certain fire conditions, traces of other toxic gases cannot be excluded. |
| Advice for firefighters | Protective clothing and self-contained breathing equipment should be carried Avoid breathing dust/fume/gas/mist/vapours/spray. |
| Protective equipment | Wear self-contained respiratory protective device. Wear fully protective suit. |
| Personal precautions, protective equipment and emergency procedures | Wear protective clothing. Use gloves, face shield Use respiratory protective device against the effects of fumes/dust/aerosol. |
| Environmental precautions | Do not allow product to reach sewage system or any water course. Inform respective authorities in case of seepage into water course or sewage system. Damp down dust with water spray. Do not allow to enter sewers / surface or ground water. |
| Methods and material for containment and cleaning up | Absorb with liquid-binding material (sand, diatomite, universal acid binders, sawdust) Use neutralizing agent. Dispose contaminated material as waste according to item 13. |
| Reference to other sections |
See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. |
| Precautions for safe handling | Keep receptacles tightly sealed and away from heat and direct sunlight. Ensure good ventilation/exhaustion at the workplace. Use gloves and wear goggles when handling. |
|---|---|
| Information about fire - and explosion protection: | Keep ignition sources away - Do not smoke. Keep respiratory protective device available. |
| Conditions for safe storage | Store in the original closed containers. Keep in a cool and dry place, avoid extreme heat and cold. |
| Requirements to be met by storerooms and receptacles: | Store only in the original receptacle. |
| Information about storage in one common storage facility: | Store away from oxidizing agents. |
| Further information about storage conditions: | Keep container tightly sealed. Protect from heat and direct sunlight. |
| Specific end use(s) | No further relevant information available. |
| Additional information about design of technical facilities: | No further data; see item 7 | |
| Control Parameters | ||
|---|---|---|
| Ingredients with limit values that require monitoring at the workplace: | ||
| 56-81-5 Glycerol PEL (Malaysia) Long-term value: 10 mg/m³ | ||
| Additional information: | The lists valid during the making were used as basis. | |
| Exposure Controls | ||
| General protective and hygienic measures: | The usual precautionary measures are to be adhered to when handling chemicals. Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. | |
| Personal protection | Hand protection: Suitable protective gloves. Eye protection: Protective goggles. Boday protection: Suitable protective clothing. | |
| Respiratory protection | Use suitable respiratory protective device only when aerosol or mist is formed. | |
| Protection of hands | Protective Gloves : The glove material has to be impermeable and resistant to the product / the substance / the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation | |
| Material of Gloves : The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. |
|
|
| Penetration time of glove material : The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. | ||
| Eye Protection | Safety glasses | |
| Parameter | Value |
|---|---|
| Chemical Name | Refined Glycerin |
| Appearance: Form | Colorless, hygroscopic & viscous liquid. (become very viscous at temperature -10 deg C and below) |
| Form | Viscous |
| Colour | Colourless |
| Odour | Odourless |
| Odour threshold | Not Determined. |
| Change in Condition | |
| Melting point/freezing point | 18.2 °C (ECHA) |
| Initial boiling point and boiling range | 290 °C (ECHA) |
| Flash point | 177 °C (Cleveland open cup) |
| Flammability (solid, gas) | Not applicable |
| Decomposition temperature | Not determined |
| Auto-ignition temperature | 370 °C (ECHA) |
| Explosive properties | Product does not present an explosion hazard. |
| Explosion limits | Lower: Not determined. Upper: Not determined. |
| Vapour pressure at 20 °C | 0.0001 hPa (ECHA) |
| Density at 20 °C | 1.26 g/cm³ (ECHA) |
| Relative density 20/20°C (g/cm3) | ≥ 1.249 (USP) |
| Evaporation rate | Not determined |
| Solubility in / Miscibility with water at 20 °C | 1000 g/L (ECHA) Fully miscible. |
| Partition coefficient: n-octanol/water | -1.75 Log Pow (OECD 107) |
| Viscosity : Dynamic: at 20 °C: | 1,412 mPas (OECD 114) |
| Other information | No further relevant information available |
| Refractive index (n20D) | ≥ 1.4731 (APAG GL 006) |
| Reactivity | No further relevant information available. |
| Chemical stability | Stable at environment temperature |
| Thermal decomposition / conditions to be avoided | No decomposition if used according to specifications. |
| Possibility of hazardous reactions | No dangerous reactions known |
| Conditions to avoid | See Section 7 for information of safe handling. |
| Incompatible materials: | See Section 7 for information of safe handling |
| Hazardous decomposition products | Carbon monoxide and carbon dioxide |
| Acute Toxicity | |||
|---|---|---|---|
|
LD/LC50 values relevant for classification 56-81-5 Glycerol |
Oral | LD50 | 27,200 mg/kg bw (Rat, Long-Evans) (Standard Acute Method) |
| Dermal | LD50 | 56,750 mg/kg bw (Guinea pig) (Standard acute method) | |
| Inhalative | LC50(4h) | 5.85 mg/L (Rat, Sprague-Dawley) (OECD 412 Subacute Inhalation Toxicity) | |
| Conclusion / Summary | No adverse effect observed. | ||
| Primary irritant effect: Skin corrosion / irritation 56-81-5 Glycerol | No irritant effect. | ||
| Irritation of skin | Irritation of skin Irritation / Corrosion 0 score (Human) (Skin - Patch Test) | ||
| Serious eye damage / irritation 56-81-5 Glycerol | No irritating effect. | ||
| Irritation of eyes | Irritation / Corrosion ≤ 2 score (Rabbit) (In vivo, fully reversible) | ||
| Respiratory or skin sensitization | Not sensitizing | ||
| 56-81-5 Glycerol | Sensitisation - Respiratory / skin sensitization : < 3 SI value (mus) (OECD 429, in vivo, LLNA) | ||
| Additional Toxicological Information | |||
| Repeated dose toxicity | Oral NOAEL (chronic toxicity): | ||
| 56-81-5 Glycerol | > 8,000 mg/kg bw/day (Rat, Long-Evans) (ECHA) | ||
| CMR effects (Carcinogenicity, mutagenicity and toxicity for reproduction) | |||
| Germ cell mutagenicity | No mutagenic effect. | ||
| 56-81-5 Glycerol | Mutagenicity - Negative Chinese hamster) (OECD 476, In vitro, SCE Assay) | ||
| Carcinogenicity | No adverse effect observed. | ||
| 56-81-5 Glycerol | Oral NOAEL 8,000 mg/kg bw/day (Rat, Long-Evans) (Carcinogenic Potential Examination) | ||
| Reproductive toxicity | No adverse effect observed. | ||
| 56-81-5 Glycerol | Oral | NOAEL (dev/fert/repro) | > 2,000 mg/kg bw/day (Rat) (Two-generation Reproductive Toxicity) |
| NOAEL (embr/tera) | > 1,180 mg/kg bw/day (Rabbit) (OECD 414) | ||
| Toxicity | |
|---|---|
| Aquatic toxicity : No adverse effect observed. 56-81-5 Glycerol | |
| Acute LC50 (96h) | 54,000 mg/L (Fish, Oncorhynchus mykiss) (ECHA) |
| Acute EC50 (48h) | 1,955 mg/L (Aquatic invertebrates,Daphnia magna) (ECHA) |
| Acute NOEC (16h) (static) | > 10,000 mg/L (Microorganism, Pseudomonas putida) (ECHA) |
| Acute NOEC (16h) (static) | > 10,000 mg/L (Microorganism, Pseudomonas putida) (ECHA) |
| Persistence and degradability | Readily biodegradable. |
| 56-81-5 Glycerol Biodegradation in water | 94 % degradation (226 mg/L, Aerobic,ECHA) |
| Behaviour in Environmental Systems | |
| Bioaccumulative potential | Does not accumulate in organisms |
| Mobility in soil | No further relevant information available |
| Additional Ecological Information | |
| General notes | Water hazard class 1 (German Regulation): slightly hazardous for water Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. |
| Results of PBT and vPvB assessment |
PBT: This product is not classified as PBT. vPvB: This product is not classified as vPvB. |
| Other adverse effects | No further relevant information available. |
| Waste treatment methods | Disposal must be made accordingly to official regulations. Do not dump into any sewers, on the ground, or into any body of water |
| Uncleaned Packaging Recommendation | Disposal must be made accordingly to official regulations. |
| Not a hazardous material according to RID/ADR, GGVS/GGVE, ADNR, IMDG, ICAO-TI/IATADGR. | |
| UN-Number | Not Regulated |
| ADR/RID/ADN, IMDG, IATA | |
| UN proper shipping name | Not Regulated |
| ADR/RID/ADN, IMDG, IATA | |
| Transport hazard class(es) | Not Regulated |
| ADR/RID/ADN, ADN, IMDG, IATA Class | |
| Packing Group | Not Regulated |
| ADR/RID/ADN, IMDG, IATA | |
| Air Transport (IATA) | Not Regulated |
| Environmental hazards | Not Regulated |
| Special precautions for user | Not Regulated |
| Transport in bulk according to Annex II of Marpol and the IBC Code | Product name : Glycerine |
| Pollution category: Z | |
| Ship type: 3 | |
| UN "Model Regulation" | Not Regulated |
| Classification and Identification. | |
|---|---|
| Symbols of danger | Not subject of the identification according to GefStoffV |
| Classification and labelling according to GHS | None |
| Classification and labelling according to EC | None |
| Safety, health and environmental regulations/legislation specific for the substance or mixture | |
| TSCA (Toxic Substances Control Act) | Substance is listed. |
| ACTIVE | |
| Canadian Domestic Substances List (DSL) | Substance is listed. |
| Philippines Inventory of Chemicals and Chemical Substances | Substance is listed. |
| Chinese Chemical Inventory of Existing Chemical Substances | Substance is listed. |
| Australian Inventory of Industrial Chemicals | Substance is listed. |
| Korean Existing Chemical Inventory | Substance is listed. |
| KE-14228 | EINECS No.: 200-289-5 |
| New Zealand Inventory of Chemicals | Substance is listed. |
| Existing Chemical Directory of Thailand (DIW) | Substance is listed. |
| TCSI - Taiwan Chemical Substance Inventory | Substance is listed. |
| Malaysia - EHS reference list | Substance is listed. |
| Russia - Register of Eurasian industrial products | Substance is listed. |
| Japan - Existing Chemical Substances | Substance is listed. |
| Vietnam - National Existing Chemical Inventory | Substance is listed. |
| GHS label elements | Not Applicable |
| Hazard pictograms | Not Applicable |
| Signal word | Not Applicable |
| Hazard statements | Not Applicable |
| Directive 2012/18/EU | Substance is not listed. |
| Named dangerous substances - ANNEX I | |
| National regulations | WGK Identification No. 116 for glycerol |
| Waterhazard class | |
| Chemical safety assessment | A Chemical Safety Assessment has been carried out. |
| This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particulars properties. | |
| Department issuing SDS | Product Safety & Regulations Department |
| Contact: Product Safety & Regulations | Info@Marsoleo.com |
| This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. | |
| Department issuing SDS: | Product Safety & Regulations Department |
| Contact: Product Safety & Regulations | Info@Marsoleo.com |
| Abbreviations and Acronyms | |
|---|---|
| RA | Read-across |
| LLNA | Local Lymph Node Assay |
| NOAEL | No Observed Adverse Effect Level |
| NOEC | No Observed Effect Concentration |
| SCE | Sister Chromatid Exchange |
| OECD | Organisation for Economic Co-operation and Development |
| DNEL | Derived No-Effect Level |
| PNEC | Predicted No-Effect Concentration |
| STP | Sewage Treatment Plant |
| ADG | The Australian Code for the Transport of Dangerous Goods by Road & Rail |
| LoS | Limit of Solubility |
| SCL | Specific Concentration Limit |
| LOEC | Lowest Observed Effect Concentration |
| SSWL | Skin Surface Water Loss |
| IMDG | International Maritime Code for Dangerous Goods |
| IATA | International Air Transport Association |
| EINECS | European Inventory of Existing Commercial Chemical Substances |
| CAS | Chemical Abstracts Service (division of the American Chemical Society) |
| LC50 | Lethal concentration, 50 percent |
| LD50 | Lethal dose, 50 percent |
| PBT | Persistent, Bioaccumulative and Toxic |
| vPvB | very Persistent and very Bioaccumulative |
| EINECS: | European Inventory of Existing Commercial Chemical Substances |
| Sources |
|---|
| CAS No. 56-81-5 Glycerol Annex 12 of Resolution MEPC.225(64) 2012 Amendments to The International Code For The Construction and Equipment of Ships Carrying Dangerous Chemicals in Bulk (IBC Code). |
| ECHA Registered Subtances Database, CAS No. 56-81-5. |
| Globally Harmonized System of Classification and Labelling of Chemicals (GHS), Third Revised Edition. |
| HSDB for CAS No. 56-81-5. |
| ICOP (2014). The Industry Code of Practice on Chemical Classification and Hazard Communication. |
| ICOP (2019). The Industry Code of Practice on Chemical Classification and Hazard Communication (Amendment). |
| ICSC (International Chemical Safety Card) 0624 (April 2006) Glycerol. |
| IMO (2020). IMDG Code International Maritime Dangerous Goods Code. Incorporating Amendment 40-20. |
| Official Journal of the European Union Commission Regulation (EU) No 453/2010. |
| Official Journal of the European Union Commission Regulation (EU) 2015/830. |
| Official Journal of the European Union Commission Regulation (EU) 2020/878 |
| Official Journal of the European Union Regulation (EC) No 1272/2008. |
| Official Journal of the European Union Regulation (EC) No 1907/2006. |
| P.U. (A) 310/2013. Occupational Safety Health (Classification, Labelling and Safety Data Sheet of Hazardous Chemicals) Regulations. |
| Data compared to the previous version altered. |
|
MARS OLEO® REFINED GLYCERINE Revision 1 (Mar 31, 2023) New issuance of GHS SDS according to ChemGes. Revision 2 (January 01, 2024) |
| Section 1 - Update product description name from GLYCERINE 99.7% USP to REFINED GLYCERINE 99.7% USP to be line with Technical Data Sheet (TDS). |
| Department issuing SDS : Product Safety & Regulations Department |
| Contact : Product Safety & Regulations - Info@Marsoleo.com |
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